北京理工大学化学与化工学院

# 北京理工大学化学与化工学院

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**Parent**: https://cce.bit.edu.cn

教师风采

教师风采

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教师风采

教师风采

## 基本信息

- [姓名：国家级青年人才 李晓芳](#)
- [职称：长聘教授/博士生导师](#)
- [电子邮箱：xfli@bit.edu.cn](#)

## 个人简介

李晓芳，有机化学和高分子化学研究所所长

十年来，本课题组立足于基础和应用研究，以“新催化剂，新聚合反应，新 材料”为宗旨，致力于开发新型的、高效、高选择性的稀土/过渡金属有机配 合物，并探索其在高分子合成（特别是配位聚合反应）和有机合成（特别是 有机方法学）中的催化作用，合成出许多具有潜在工业应用前景的聚烯烃或者难以用以往催化剂制备的新型高分子材料和有机合成试剂。主持国家自然 科学基金项目 6 项、承担企业合作项目 1 项；参与国家自然科学基金项目等1 项。迄今在国内外学术刊物及会议上发表学术论文 60 余篇，其中 SCI 收录61 篇，EI 收录 0 篇，获授权专利 9 项。

荣誉奖励

2013 年国家级青年人才项目

2013 年教育部新世纪人才称号获得者

北京理工大学杰出中青年教师发展支持计划 (2009)

承担项目

1. 稀土催化烯烃与极性烯烃配位共聚合反应制备功能化聚烯烃；面上项 目，国家自然科学基金委；66 万元；起始时间：2020, 01；终止时间： 2023, 12；主持。

2. 稀土金属催化剂络合物的合成及放大研究；中国石油天然气股份有限公 示石油化工研究院；50 万元；起始时间：2019, 11；终止时间：2021, 12； 主持。

3. 金属有机化合物置换型荧光探针荧光检测烯烃配位聚合反应的催化活

性物种；面上项目，国家自然科学基金委；63 万元；起始时间：2018, 01；终止时间：2021, 12；主持。

4. 基于三键化学的高分子合成（主持人：唐本忠院士）：21490570，子课 题：新型基于三键的聚合反应和方法（负责人：唐本忠院士）：21490574； 重大项目，国家自然科学基金委；150/2000 万元；起始时间：2015, 01， 终止时间：2019, 12，参与。

5. 高分子合成化学；国家级青年人才项目，国家自然科学基金委；100 万元；起始时间：2014, 01；终止时间：2016, 12；主持。

6. 稀土催化剂合成；新世纪人才支持计划，教育部；50 万元；起始时间：

2014, 01；终止时间：2015, 12；主持。

7. 稀土催化剂通过配位共聚合方法制备高立构规整性 1,3-环己二烯基共聚 物；面上项目，国家自然科学基金委；82 万元；起始时间：2013, 01； 终止时间：2016, 12；主持。

8. 稀土催化剂促进烯烃和共轭二烯烃配位共聚合反应的研究；面上项目， 国家自然科学基金委；38 万元；起始时间：2010, 01；终止时间：2012, 12；主持。

9. 稀土-锌簇催化二氧化碳和环氧烷烃共聚合反应；人事部留学人员科技 活动项目择优资助优秀项目；4 万元；起始时间：2011, 01；终止时间： 2012, 12；主持。

10. 非茂阳离子型稀土金属烯烃聚合催化剂的研究；教育部留学回国人员启 动经费项目；4 万元；起始时间：2009, 09；终止时间：2010, 09；主持。

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## 研究领域和方向

1. 稀土/过渡金属有机化学\
2. 高分子合成化学\
3. 烯/炔烃配位聚合反应\
4. 有机方法学\

## 教育背景

2000.09-2003.12 中国科学院长春应用化学研究所，有机化学专业，理学博士\
1997.09-2000.07 东北师范大学，有机化学专业，理学硕士\
1993.09-1997.07 东北师范大学，化学教育专业，理学学士\

## 工作履历

2008.02-至今 北京理工大学化学与化工学院，长聘教授/博士生导师/有机\
所所长\

## 研究成果

十年来，我们立足于基础和应用研究，以“新催化剂，新聚合反应，新 材料”为宗旨，致力于开发新型的、高效、高选择性的稀土/过渡金属有机配 合物，并探索其在高分子合成（特别是配位聚合反应）和有机合成（特别是 有机方法学）中的催化作用，合成出许多具有潜在工业应用前景的聚烯烃或者难以用以往催化剂制备的新型高分子材料和有机合成试剂。主持国家自然 科学基金项目 6 项、承担企业合作项目 1 项；参与国家自然科学基金项目等1 项。迄今在国内外学术刊物及会议上发表学术论文 60 余篇，其中 SCI 收录61 篇，EI 收录 0 篇，获授权专利 9 项。\
代表性论 文（近 五年以 来） \
1. H. Liu,a S.-W. Zhang,a X.-Q. Yan,a C. Song,a J.-P. Chen,a Y.-P. Dong\*b and X.-F. Li\*a. Silylium Cations Initiated Sergeants-and-Soldiers Type Chiral Amplification of Helical Aryl Isocyanide Copolymers. Polymer Chemistry, 2020, 11, 6017-6028. \
2. L. Zhang,a Q.-B. Cao,a F. Gao,a Y.-P. Dong\*b and X. - F. Li\*. Self-Supported Rhodium Catalysts Based on a Microporous Metal-Organic Framework for Polymerization of Phenylacetylene and Its Derivatives. Polymer Chemistry, 2020, 11, 2904-2913. \
3. X.-L. Wu, X.-W. Yan, Z. Yang, S.-W. Zhang, Y.-P. Dong\*, J.-G. Zhi\* and X.- F. Li\*. AliBu3: Unprecedented Main-Group Metal Catalyst for Helical-Sense- Selective Polymerization of Chiral Aryl Isocyanides and Copolymerization with Achiral Aryl Isocyanides. Mater. Chem. Front.2019, 3, 1192-1198. \
4. X.-L. Wu, P.-F. Zhang, S.-W. Zhang, Z. Yang, W.-J. Chi, G. Guo, H. Liu, Y.-P. Dong\*, N.-N. Qiu\*, L. Yan and X. - F. Li\*. Polymerization of phenylacetylenes by binuclear rhodium catalysts with different para- binucleating phenoxyiminato linkages. Polymer Chemistry, 2019, 10, 4163- 4172. \
5. G. Guo, X.-L. Wu, X.-Q. Yan, Y. Li, X. - F. Li\*, S.-W. Zhang\* and N.-N. Qiu\*. Unprecedentedly High Activity and/or High Regio-/Stereoselectivity of Fluorenyl-Based CGC Allyl-Type η3: η1-tert-Butyl (dimethylfluorenylsilyl) amido Ligated Rare Earth Metal Monoalkyl Complexes in Olefin Polymerization. Polymers, 2019, 5, 836. \
6. X.-W. Yan, S.-W. Zhang, P.-F. Zhang, X.-L. Wu, A. Liu, G. Guo, Y.-P. Dong\* and X.- F. Li\*.[Ph3C][B(C6F5)4]: A Highly Efficient Metal‐Free Single‐ Component Initiator for the Helical ‐ Sense ‐ Selective CationicCopolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides.Angewandte Chemie International Edition, 2018, 57, 8947–8952. \
7. X.-L. Wu, Z. Yang, X.-W. Yan, P.-F. Zhang, L. Wang, G. Guo, Y.-P. Dong and X. - F. Li \*. Polymerization of 1-Chloro-2-Phenylacetylenes by Cationic Monoanionic Tridentate (S,S)-Bis(oxazolinylphenyl)amido-Ligated Palladium Catalysts: Is It Coordination-Insertion Mechanism? Polymer Chemistry, 2018, 9, 4856-4865. \
8. F. Gao L. Zhang C. Yu X.-W. Yan S.-W. Zhang X. - F. Li \*. Controlled Polymerization of Isoprene with Chromium ‐ Based Metal ‐ Organic Framework Catalysts: Switching from Cyclic to cis ‐ 1,4 ‐ Selectivity Depending on Activator. Macromolecular Rapid Communications, 2018, 39, 1800002\
9. D.-Q. Peng, X.-W. Yan, S.-W. Zhang\*, X. - F. Li \*. Syndiotactic Polymerization of Styrene and Copolymerization with Ethylene Catalyzed by Chiral Half-sandwich Rare-earth Metal Dialkyl Complexes. Chinese Journal of Polymer Science, 2018, 36, 222−230. \
10. C. Yu, P.-F. Zhang, F. Gao, S.-W. Zhang\* and X.- F. Li\*. A Displacement-type Fluorescent Probe Reveals Active Species in the Coordinative Polymerization of Olefins. Polymer Chemistry, 2018, 9, 603–610. \
11. X.-W. Yan, S.-W. Zhang, D.-Q. Peng, P.-F. Zhang, J.-G. Zhi, X.-L.Wu, L. Wang, Y.-P. Dong \* and X. -F. Li \*. Cationic Half-sandwich Rare-earth Metal Alkyl Species Catalyzed Polymerization Copolymerization of Aryl Isocyanides Possessing Polar, Bulky, or Chiral Substituents. Polymer Chemistry, 2018, 9, 984–993. \
12. X.-Q. Yan, F.-Z. Yang\*, G.-L. Cai, Q.-W. Meng, and X. - F. Li\*. Nickel(0)- Catalyzed Inert C-O Bond Functionalization: Organo Rare-Earth Metal Complex as the Coupling Partner. Organic Letters, 2018, 20, 624−627. \
13. P.-F. Zhang, H.-Y. Liao, H.-H. Wang, X.- F. Li \*. F.-Z. Yang\*, and S.-W. Zhang\*. Cis-1,4-Polymerization of Isoprene Catalyzed by 1,3-Bis(2- pyridylimino)isoindoline-Ligated Rare-Earth-Metal Dialkyl Complexes .Organometallics, 2017, 36, 2446–2451. \
14. C. Yu, D.-H. Zhou, X.-Q. Yan, F. Gao, L. Zhang, S.-W. Zhang\* and X. - F. Li \*. Cis-1,4-Polymerization of Isoprene by 1,3- Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. Polymers, 2017, 9, 531-542. \
15. F.-Z. Yang, X. - F. Li \*. Novel Cationic Rare Earth Metal Alkyl Catalysts for Precise Olefin Polymerization. Journal of Polymer Science, Part A: Polymer Chemistry. 2017, 55, 2271–2280. \
16. Y. Tian, X. - F. Li \*, J.-B. Shi, B. Tong, Y.-P. Dong\*. Monomer-induced Switching of Stereoselectivity and Limitation of Chain Growth in the Polymerization of Amine-containing Para-substituted Phenylacetylenes by [Rh(norbornadiene)Cl]2. Polymer Chemistry, 2017, 8, 5761-5768. \
17. Y.-D. Huang, J.-Y He, Z.-X. Liu, P.-F. Zhang, G.-L. Cai, S.-W. Zhang, and X. - F. Li \*. A Highly Active Chiral (S, S)-Bis(oxazoline) Pd(II) Alkyl Complex/Activator Catalytic System for Vinyl Polymerization of Norbornene in Air and Water. Polymer Chemistry, 2017, 8, 1217-1222. \
18. Y.-D. Huang, J.-Y. He, G.-L. Cai, Z.-X. Liu, T.-T. Li, T.-T. Du, S.-W. Zhang, B. Yao, and X. - F. Li \*. cis-1,4-Specific Carbocationic Polymerization and Copolymerization of 1,3-Dienes Initiated by (S,S)- Bis(oxazolinylphenyl)amine Chromium Complexes. Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55, 1250–1259. \
19. G.-X. Du, X.-W. Yan, P.-F. Zhang, H.-H. Wang, Y.-P. Dong, X.- F. Li\*. 1,4-Specific Copolymerization of 1,3-Cyclohexadiene with Isoprene and Their Terpolymerization with Styrene by Cationic Half-Sandwich Fluorenyl Rare Earth Metal Alkyl Catalysts, Polymer Chemistry, 2017, 8, 698-707. \
20. P.-F. Zhang, H.-H. Wang, X.-S. Shi, X.-W. Yan, X.-L. Wu, S.-W. Zhang, B. Yao, X. Feng, J.-G. Zhi, X.- F. Li\* , B. Tong, J.-B. Shi, L. Wang, Y.-P. Dong\*. On-Water Polymerization of Phenylacetylene Catalyzed by Rh Complexes Bearing Strong π-Acidic Dibenzo[a,e]cyclooctatetraene Ligand. Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55, 716–725, Special Issue for Prof. Ben Zhong Tang. \
21. G.-L. Cai, Y.-D. Huang, T.-T. Du, S.-W. Zhang, B. Yao\*, X.- F. Li\*, Palladium-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Homoleptic Rare- Earth Metal Trialkyl Complexes with Aryl Bromides: Efficient Synthesis of Functionalized Benzyltrimethylsilanes, Chemical Communications, 2016, 52, 5425‒5427. \
22. G.-l. Cai, Z.-B. Zhou, W.-C. Wu, B. Yao,\* S.-W. Zhang, X. - F. Li\*. Pd- Catalyzed C(sp3)–C(sp2) Cross-Coupling of Y(CH2SiMe3)3(THF)2 with Vinyl Bromides and Triflates, Organic & Biomolecular Chemistry, 2016, 14, 8702– 8706. \
23. D.-Q. Peng, X.-W. Yan, C. Yu, S.-W. Zhang, X.- F. Li\* . Transition Metal Complexes Bearing Tridentate Ligands for Precise Olefin Polymerization, Polymer Chemistry, 2016, 7, 2601–2634. \
24. D.-Q. Peng, G.-X. Du, P.-F. Zhang, B. Yao, X.- F. Li\*, S.-W. Zhang\*. Regio- and Stereochemical Control in Ocimene Polymerization by Half-Sandwich Rare-Earth Metal Dialkyl Complexes, Macromolecular Rapid Communications, 2016, 37, 987‒992. \
25. G.-X. Du, Y.-Y. Long, J.-P. Xue, S.-W. Zhang, Y.-P. Dong, X. - F. Li\*. 1,4-Selective Polymerization of 1,3-Cyclohexadiene and Copolymerization with Styrene by Cationic Half-Sandwich Fluorenyl Rare Earth Metal Alkyl Catalysts, Macromolecules, 2015, 48, 1627‒1635. \
26. G.-X. Du, J.-P. Xue, D.-Q. Peng, C. Yu, H.-H. Wang, Y.-N. Zhou, J.-J. Bi, S.-W. Zhang, Y.-P. Dong, X. - F. Li\*. Copolymerization of Isoprene with Ethylene Catalyzed by Cationic Half-Sandwich Fluorenyl Scandium Catalysts, Journal of Polymer Science, Part A: Polymer chemistry, 2015, 53, 2898–2907. \
27. S.-Q. Liu, G.-X. Du, J.-Y. He, Y.-Y. Long, S.-W. Zhang\*, X.- F. Li\*. Cationic Tropidinyl Scandium Catalyst: A Perfectly Acceptable Substitute for Cationic Half-Sandwich Scandium Catalysts in cis-1,4-Polymerization of Isoprene and Copolymerization with Norbornene, Macromolecules, 2014, 47, 3567‒3573. \
28. H. Liu, J.-Y. He, Z.-X. Liu, Z.-G. Lin, G.-X. Du, S.-W. Zhang,\* and X.- F. Li \*. Quasi-Living trans-1,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Bearing a Chiral (S,S)- Bis(oxazolinylphenyl)amido Ligand, Macromolecules 2013, 46, 3257‒3265. \
 以第一作 者发表 的 代表 性 论文 (2004-2010) \
1. X. - F. Li , Z.-M. Hou\*. Scandium-Catalyzed Regio- and Stereospecific cis- 1,4-Polymerization of 1,3-Cyclohexadiene and Copolymerization with Ethylene, Macromolecules, 2010, 43, 8904‒8909. \
2. X. - F. Li, M. Nishiura, L.-H. Hu, K. Mori, Z.-M. Hou\*. Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls, Journal of the American Chemical Society, 2009, 131, 13870‒13882. \
3. X. - F. Li , Z.-M. Hou\*. Organometallic Catalysts for Copolymerization of Cyclic Olefins, Coordination Chemistry Reviews, 2008, 252, 1842‒1869. \
4. X. - F. Li, M. Nishiura, K. Mori, T. Mashiko, Z.-M. Hou\*. Cationic Scandium Aminobenzyl Complexes. Synthesis, Structure and Unprecedented Catalysis of Copolymerization of 1-Hexene and Dicyclopentadiene, Chemical Communications, 2007, 40, 4137‒4139. \
5. X. - F. Li, J. Baldannis, M. Nishiura, O. Tardif, Z.-M. Hou\*. Cationic Rare- Earth Polyhydrido Complexes: Synthesis, Structure, and Catalytic Activity for the cis-1,4-Selective Polymerization of 1,3-Cyclohexadiene, Angewandte Chemie International Edition, 2006, 45：8184‒8188. \
6. X. - F. Li , J. Baldamus, Z.-M. Hou\*. Alternating Ethylene-Norbornene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes, Angewandte Chemie International Edition, 2005, 44, 962‒965. \
7. X. - F. Li , Z.-M. Hou\*. Scandium-Catalyzed Copolymerization of Ethylene with Dicyclopentadiene and Terpolymerization of Ethylene, Dicyclopentadiene, and Styrene, Macromolecules, 2005, 38, 6767‒6769. \
8. X. - F. Li, K. Dai, W.-P. Ye, L. Pan, Y.-S. Li\*. New Titanium Complexes with Two Beta-Enaminoketonato Chelate Ligands: Syntheses, Structures, and Olefin Polymerization Activities, Organometallics, 2004, 23, 1223‒1230.\